Modelling of Octahedral Manganese II Complexes with Inorganic Ligands: A Problem with Spin-States
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چکیده
Quantum mechanical ab initio UHF, MP2, MC-SCF and DFT calculations with moderate Gaussian basis sets were performed for MnX6, X = H2O, F, CN, manganese octahedral complexes. The correct spin-state of the complexes was obtained only when the counter ions neutralizing the entire complexes were used in the modelling at the B3LYP level of theory.
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تاریخ انتشار 2003